Tannin determination in young coconut coir (Cocos nucifera L.) by FTIR and UV-Vis spectroscopy
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Published:
Mar 30, 2023
Keywords:
Coconut husk, Condensed tannin, Polyphenolic, Secondary metabolites, Spectroscopy
Section
Chemistry
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Abstract
The coir of young coconut is the largest by product of coconut. Young coconut coir has no important industrial uses and until now has been incinerated or dumped without control. This is because the utilization of young coconut coir is not easy as the old one. Tannin has pharmacological activities including anti-inflammatory, antioxidant, anti-tumor This study aims to determine tannin in young coconut coir (Cocos nucifera L.) using a complementary analytical technique, Fourier Transform Infra-RedFTIR) and Ultraviolet-Visible (UV-Vis) spectroscopy. Sample of young coconut coir was obtained from the waste of bargainer at the local market. Sample was maserated using ethanol as the solvent and then was evaporated to get concentrated extract. The FTIR and UV-Vis spectra showed that the sample was indicated to contain tannin. The presence of tannin was indicated by appearance of peak at 283 nm and 326 nm in UV-Vis spectra and in the region between 1610-1445 cm-1 by FTIR. This research is an early stage in the characterization of tannin compounds from young coconut coir extract. It is expected that waste have economic value in the future.
Article Details
How to Cite
Sari, Y. (2023). Tannin determination in young coconut coir (Cocos nucifera L.) by FTIR and UV-Vis spectroscopy. Jurnal Matematika Dan Ilmu Pengetahuan Alam LLDikti Wilayah 1 (JUMPA), 3(1), 08–13. https://doi.org/10.54076/jumpa.v3i1.271
References
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Falcão, L., & Araújo, M. E. M. (2018). Vegetable tannins used in the manufacture of historic leathers. Molecules, 23(5), 1–20. https://doi.org/10.3390/molecules23051081
Fouladvandi, B., & Elhami, S. (2017). Ultra-Trace Determination of Silver in Water, Soil and Radiology Film Samples Using Dispersive Liquid-Liquid Microextraction and Microvolume UV–Vis Spectrophotometry. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36(6), 163–170.
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Ricci, A., Olejar, K. J., Parpinello, G. P., Kilmartin, P. A., & Versari, A. (2015). Application of Fourier transform infrared (FTIR) spectroscopy in the characterization of tannins. Applied Spectroscopy Reviews, 50(5), 407–442. https://doi.org/10.1080/05704928.2014.1000461
Sari, Y., Yulis, P. A. R., Putri, I. I., Putri, A. M., & Anggraini, S. (2021). Penentuan Kandungan Metabolit Sekunder Ekstrak Etanol Sabut Kelapa Muda ( Cocos nucifera L .) Secara Kualitatif. Journal of Research and Education Chemistry (JREC), 3(2), 113–121.
Sholikhah, U. N., Pranowo, D., Arvianto, R. I., Sarmini, E., & Widyaningrum, T. (2020). Purification Method of Silver Nanoparticles (AgNPs) and its Identification Using UV-Vis Spectrophotometer. Key Engineering Materials, 840, 484–491.
Sirisangsawang, R., & Phetyim, N. (2023). Optimization of tannin extraction from coconut coir through response surface methodology. Heliyon, 9(2), e13377. https://doi.org/10.1016/j.heliyon.2023.e13377
Tajodini, N., Moghimi, A., & Karimnezhad, K. (2020). Separation of levodopa using Nanotubes Carbon modified Methyl Amine in biological samples and determination by UV-Vis Spectrophotometry. Journal of Advanced Pharmacy Education & Research| Oct-Dec, 10(S4).
Weli, A. M., Al-Salmi, S., Al Hoqani, H., & Hossain, M. A. (2018). Biological and phytochemical studies of different leaves extracts of Pteropyrum scoparium. Beni-Suef University Journal of Basic and Applied Sciences, 7(4), 481–486.
Xiong, P., Qin, S. han, Li, K. lin, Liu, M. juan, Zhu, L., Peng, J., Shi, S. lin, Tang, S. nv, Tian, A. ping, & Cai, W. (2021). Identification of the tannins in traditional Chinese medicine Paeoniae Radix Alba by UHPLC-Q-Exactive Orbitrap MS. Arabian Journal of Chemistry, 14(11), 103398. https://doi.org/10.1016/j.arabjc.2021.103398
Zhang, A., Li, J., Zhang, S., Mu, Y., Zhang, W., & Li, J. (2017). Characterization and acid-catalysed depolymerization of condensed tannins derived from larch bark. RSC Advances, 7(56), 35135–35146. https://doi.org/10.1039/c7ra03410e
Cano, A., Contreras, C., Chiralt, A., & González-Martínez, C. (2021). Using tannins as active compounds to develop antioxidant and antimicrobial chitosan and cellulose based films. Carbohydrate Polymer Technologies and Applications, 2. https://doi.org/10.1016/j.carpta.2021.100156
Das, A. K., Islam, M. N., Faruk, M. O., Ashaduzzaman, M., & Dungani, R. (2020). Review on tannins: Extraction processes, applications and possibilities. In South African Journal of Botany (Vol. 135, pp. 58–70). Elsevier B.V. https://doi.org/10.1016/j.sajb.2020.08.008
Dutta, A. (2017). Fourier transform infrared spectroscopy. Spectroscopic Methods for Nanomaterials Characterization, 73–93.
Falcão, L., & Araújo, M. E. M. (2018). Vegetable tannins used in the manufacture of historic leathers. Molecules, 23(5), 1–20. https://doi.org/10.3390/molecules23051081
Fouladvandi, B., & Elhami, S. (2017). Ultra-Trace Determination of Silver in Water, Soil and Radiology Film Samples Using Dispersive Liquid-Liquid Microextraction and Microvolume UV–Vis Spectrophotometry. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36(6), 163–170.
Gourlay, G., & Constabel, C. P. (2019). Condensed tannins are inducible antioxidants and protect hybrid poplar against oxidative stress. Tree Physiology, 39(3), 345–355. https://doi.org/10.1093/treephys/tpy143
Grasel, F. dos S., Ferrão, M. F., & Wolf, C. R. (2016). Ultraviolet spectroscopy and chemometrics for the identification of vegetable tannins. Industrial Crops and Products, 91, 279–285. https://doi.org/10.1016/j.indcrop.2016.07.022
Guedes, D. (Douglas), Martins, G. (Gabriel), Alviano, D. S. (Daniela), Lutterbach, M. T. S. (Marcia), Reznik, L. Y., & Sérvulo, E. F. (2018). Coconut Husk Fiber Proanthocyanidins: Ecofriendly Corrosion Inhibitor, Ecotoxicity and Biocide Activity. International Journal of Engineering and Technical Research, 8(2), 27–29.
Ju, Y. lun, Yang, L., Yue, X. feng, He, R., Deng, S. lin, Yang, X., Liu, X., & Fang, Y. lin. (2021). The condensed tannin chemistry and astringency properties of fifteen Vitis davidii Foex grapes and wines. Food Chemistry: X, 11(April), 100125. https://doi.org/10.1016/j.fochx.2021.100125
Maku?a, P., Pacia, M., & Macyk, W. (2018). How to correctly determine the band gap energy of modified semiconductor photocatalysts based on UV–Vis spectra. In The journal of physical chemistry letters (Vol. 9, Issue 23, pp. 6814–6817). ACS Publications.
Marques, S. R. R., Azevêdo, T. K. B., de Castilho, A. R. F., Braga, R. M., & Pimenta, A. S. (2021). Extraction, quantification, and ftir characterization of bark tannins of four forest species grown in northeast brazil. Revista Arvore, 45, 1–10. https://doi.org/10.1590/1806-908820210000041
Mohamed, M. A., Jaafar, J., Ismail, A. F., Othman, M. H. D., & Rahman, M. A. (2017). Fourier transform infrared (FTIR) spectroscopy. In Membrane characterization (pp. 3–29). Elsevier.
Morbeck, F. L., Lelis, R. C. C., Schueler, M. V. E., Santos, W. A., Sampaio, D. A., Da Silva, B. C., Morais, R. D. M., & Santana, G. M. (2019). Extraction and evaluation of tannin from green coconut mesocarp. Revista Materia, 24(3). https://doi.org/10.1590/s1517-707620190003.0748
Okafor, E. G., Abba, M. T., Ubadike, O. C., Agbo, S., & Muhammad, M. H. (2021). Fourier-Transform Infrared Spectroscopy and Thermal Investigation of Hybrid Banana/Sisal Fiber Reinforced Polyester Matrix Composite. Advanced Materials Research, 1165, 39–46.
Panzella, L., & Napolitano, A. (2022). Condensed Tannins, a Viable Solution to Meet the Need for Sustainable and Effective Multifunctionality in Food Packaging: Structure, Sources, and Properties. Journal of Agricultural and Food Chemistry, 70(3), 751–758. https://doi.org/10.1021/acs.jafc.1c07229
Passos, M. L. C., & Saraiva, M. L. M. F. S. (2019). Detection in UV-visible spectrophotometry: Detectors, detection systems, and detection strategies. Measurement, 135, 896–904.
Picollo, M., Aceto, M., & Vitorino, T. (2018). UV-Vis spectroscopy. Physical Sciences Reviews, 4(4), 20180008.
Ricci, A., Olejar, K. J., Parpinello, G. P., Kilmartin, P. A., & Versari, A. (2015). Application of Fourier transform infrared (FTIR) spectroscopy in the characterization of tannins. Applied Spectroscopy Reviews, 50(5), 407–442. https://doi.org/10.1080/05704928.2014.1000461
Sari, Y., Yulis, P. A. R., Putri, I. I., Putri, A. M., & Anggraini, S. (2021). Penentuan Kandungan Metabolit Sekunder Ekstrak Etanol Sabut Kelapa Muda ( Cocos nucifera L .) Secara Kualitatif. Journal of Research and Education Chemistry (JREC), 3(2), 113–121.
Sholikhah, U. N., Pranowo, D., Arvianto, R. I., Sarmini, E., & Widyaningrum, T. (2020). Purification Method of Silver Nanoparticles (AgNPs) and its Identification Using UV-Vis Spectrophotometer. Key Engineering Materials, 840, 484–491.
Sirisangsawang, R., & Phetyim, N. (2023). Optimization of tannin extraction from coconut coir through response surface methodology. Heliyon, 9(2), e13377. https://doi.org/10.1016/j.heliyon.2023.e13377
Tajodini, N., Moghimi, A., & Karimnezhad, K. (2020). Separation of levodopa using Nanotubes Carbon modified Methyl Amine in biological samples and determination by UV-Vis Spectrophotometry. Journal of Advanced Pharmacy Education & Research| Oct-Dec, 10(S4).
Weli, A. M., Al-Salmi, S., Al Hoqani, H., & Hossain, M. A. (2018). Biological and phytochemical studies of different leaves extracts of Pteropyrum scoparium. Beni-Suef University Journal of Basic and Applied Sciences, 7(4), 481–486.
Xiong, P., Qin, S. han, Li, K. lin, Liu, M. juan, Zhu, L., Peng, J., Shi, S. lin, Tang, S. nv, Tian, A. ping, & Cai, W. (2021). Identification of the tannins in traditional Chinese medicine Paeoniae Radix Alba by UHPLC-Q-Exactive Orbitrap MS. Arabian Journal of Chemistry, 14(11), 103398. https://doi.org/10.1016/j.arabjc.2021.103398
Zhang, A., Li, J., Zhang, S., Mu, Y., Zhang, W., & Li, J. (2017). Characterization and acid-catalysed depolymerization of condensed tannins derived from larch bark. RSC Advances, 7(56), 35135–35146. https://doi.org/10.1039/c7ra03410e
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